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2024 Theses Doctoral

Bridging the Gap Between Lab Technology and Large-Scale Application: A Technological Study of Carbon Dioxide Direct Air Capture Sorbents and Direct Air Capture In-Situ Methanation Dual Function Materials

Lin, Yuanchunyu

This thesis aims to provide different aspects to make the Direct Air Capture Dual Function Materials (DAC-DFM) project more applicable in commercialization and large-scale deployment to directly address the global warming problem caused by anthropogenic CO₂. Dual function materials are comprised of nano dispersed alkaline sorbents and a methanation catalyst to capture CO₂ from ambient air and convert it to CH₄ upon the addition of green H₂. Two sub-projects named “Ru thrifting project” and “hydrophobicity/surface modification project” were performed to study the potential optimization and tradeoff when modifying the DFM components. The major accomplishment in this thesis has been the thrifting of Ru from its original value of 5% to 1% and finally 0.25% with no sacrifice in stability but with some decrease in capacity for CO₂ capture and methanation. Given the Ru unit price (around 14 USD/g, flexible market, in March 2024), this approach would greatly reduce the overall production cost. In the hydrophobicity/surface modification project, Al₂O₃ the high surface area carrier for the DFM components, was treated using 3 different methods (high temperature calcination, acid treatment, and metal oxide doping). The goal of this study was to reduce the surface water uptake in the Al₂O₃ from humidity, present in ambient air, by increasing hydrophobicity to reduce the energy evaporation cost during temperature swing in the DFM CO₂ desorption/methanation process. Samples treated after these 3 methods showed a significant decrease in water uptake. ZrO₂ doped Na₂CO₃-Al₂O₃ sample showed a low H₂O uptake and the highest CO₂ adsorption, twice that of the CO₂ capacity of the Na₂CO₃-Al₂O₃ samples treated by calcination and acid. Such hydrophobicity study would be used to further optimize the components of DFM to meet requirements in real world applications. Future outlook for DFMs is also briefly discussed with focuses on (1) using pre-heated H₂ to increase the temperature of inner DFM coatings for increased energy efficiency, (2) increased CO₂ capture, utilization, and conversion to CH₄, as well as (3) practical acceptance of DAC hubs and CO₂ taxes/credits. A new approach of moisture swing DAC sorbents as an alternate technology to the thermal swing DFM is suggested as a future project. With loaded CO₃²⁻ on both organic ion exchange particles/membranes and inorganic silica-based granules, the CO₂ adsorption/desorption effect can be controlled by the moisture level (relative humidity) from ambient air in the inlet sample chamber.

  • Environmental engineering
  • Carbon dioxide
  • Carbon dioxide--Absorption and adsorption
  • Carbon sequestration
  • Carbon dioxide mitigation
  • Zirconium oxide

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COMMENTS

  1. PDF M. Tech Thesis Format Final

    This final copy of the thesis must be submitted to Academic section (Assistant Registrar, Academics) through the M. Tech. program Coordinator/Advisor. A soft copy of the thesis on a Compact Disk must also be submitted along with the hard copy of the thesis. 1.2. Title of the Thesis and Title page format.

  2. PDF GUIDELINES FOR PREPARING THE THESIS

    The purpose of this manual is to provide broad guidelines to the Ph.D./ M.Tech./ M.Pharm. candidates for the preparation of the thesis. It lists the general and specific requirements governing the thesis preparation including guidelines for structuring the contents. The candidates are advised to have thoroughly gone through the up-to-date Ph.D ...

  3. PDF Thesis format for BTech and MTech (final)

    Paragraph format: Set 10 pt or 12 pt space either before or after (not both) paragraph. 9. Indentation in paragraphs: No indentation in the first paragraph (under each heading) but an indentation of 5 space bars for all subsequent paragraphs (under the same heading). 10.

  4. PDF GUIDELINES FOR THESIS PREPARATION

    2.1.2 The thesis must be printed or photocopied on both sides of white paper. All copies of thesis pages must be clear, sharp and even, with uniform size and uniformly spaced characters, lines and margins on every page of good quality white paper of 75 gsm or more. 2.1.3 Thesis should be free from typographical errors.

  5. PDF Guidelines for M. Tech. Dissertation/ Thesis

    The final exam will have Presentation followed by Viva-Voce at the college of study. Three hard bound copies of M. Tech. Dissertation/Thesis duly certified by the Guide (supervisor) and forwarded by Head of the Department/ Head of the Institute be submitted to Assistant CoE, BTU. Title of Thesis, name of the student and supervisor, year of ...

  6. PDF Thesis Guidelines

    National Institute of Technology, Tiruchirappalli - 620 015. Thesis Guidelines 1 THESIS The arrangement of parts of B.Tech. / M.Tech. / M.S. / Ph.D. Thesis The sequence in which the thesis material should be arranged and bound should be as follows: 1. Cover page 2. Inside cover page 3. Dedication page (Optional) 4. Bonafide Certificate 5.

  7. PDF GUIDELINES FOR THE PREPERATION OF M.Tech. DISSERTATION REPORT

    3 AUXILIARY FORMAT 3.1 Binding: The evaluation copies of the Dissertation report may be spiral bound or soft bound. The final hard bound copies need to be submitted after the viva-voce examination with the following color specification: M.Tech. Dissertation work Grey 3.2 Front Covers: The front covers shall contain the following details:

  8. PDF General Guidelines for Preparation of M.tech. Dissertation

    OUTER COVER AND TITLE PAGE (as per format given in Appendix I) The outer cover of M.Tech. dissertation should be in light blue color with black printing. Type the title of the dissertation using capital letters throughout. If it occupies more than one line, double space between lines and arrange it in inverted pyramid form.

  9. PDF M.TECH THESIS FORMAT Paper Font Size and Margins

    ndard A 4 (height 297 mm, width 210 mm), 90GSM.The the. oth sides of white paper.Font Size and Margins:The standard font of the text shall be Times New R. an of 12 or Arial 11 pts with 1.5 line spacing.Font size of Chapter, headin. ub heading will be on the Authors discretion. The top, bottom and right side margins should be 25 mm, whereas the ...

  10. PDF Microsoft Word

    However, the title of a Book, Ph.D. Thesis, M. Tech. Thesis, B. Tech Thesis and a Technical report is written in Itallic. iv Case-II: If References expressed by Sir Name followed by Year of Publication in the ... THESIS FORMAT 1. Paper Quality The thesis shall be printed/xeroxed on white bond paper, whiteness 95% or above, weight 70

  11. PDF Shri G.S. Institute of Technology and Science Indore (M.P.)

    of thesis/dissertation/report with the following color specification: Specimen Color Of Binding Material Color Of Lettering On The Specimen M.Tech / M.E. Sky Blue Black Blank Sheets In addition to the white sheets (binding requirement) two white sheets shall be put at the beginning and the end of the thesis. PART A

  12. PDF PHASE I REPORT & PHASE II THESIS

    MANUAL FOR PREPARATION OF M. The Report /Thesis (at the time of submission) should have the following page margins : Top edge Bottom edge Left side : : : 30 to 35 mm. 25 to 30 mm. 35 to 40 mm Right side : 20 to 25 mm. The report/thesis should be prepared on good quality white paper preferably not lower than 80 gsm.

  13. PDF General Guidelines for Preparation of M.tech. Dissertation

    lege, Chandigarh (Deemed to be University)LAYOUT Font The Dissertation should. written in Indian/British English. n A4 size bond paper.Font should be Times New Roman. 12.Same font should be used throughout the dissertation. If necessary, different fo. s may be used within the Tables, Figures, and Appendices.

  14. PDF Guidelines

    the thesis shall be prepared in M.S. word/Latex. The same format shall also be followed in preparation of the final soft and hard copies to be submitted to the Department and Library in future. While writing the thesis care must be taken that no short forms should be used in the thesis such as Expt, Temp., Eqn, deg., Pr. etc. in the text. The ...

  15. PDF Guidelines for Preparation of Thesis / Dissertation/Reports

    0-85 GSM (gram per square meter) or more. 3.3. Paper sizeThe standard size of paper of a thesis is 21.5 cm (8.5 inches) wid. and 28 (11 inches) long, commonly known as A4 sized paper.Oversized figures and tables if any should. be reduced appropriately to fit with the size of the paper. Care should be taken n.

  16. PDF Guidelines for M. Tech. Dissertation/ Thesis

    Institute) of M. Tech. Dissertation/Thesis. Bio-data of Guide is to be attached. e) One copy of the forwarding letter (by Head of the Institute) must be sent to the Dean (Faculty of Engg. & Tech.) in addition to sending it to the Dy. Registrar (Secy.) RTU. f) The main contents in the Dissertation/ Thesis should be typed in Times New Roman 12 font

  17. LIB

    Theses and dissertation section have all the hard copy of Ph.D. theses and M-Tech dissertations after the conversation into an IIT (BHU), Varanasi. The theses and dissertations before 2012 may get access from the Central Library, Banaras Hindu University. The section also maintained a soft copy of Ph.D. theses in CD form as well as in online ...

  18. PDF Manual

    Process for Evaluation of Exec. M.Tech. 6.8.6.9 Thesis 44 Process for Evaluation of Integrated M.Tech. & Dual 6.8.6.10 Degree Thesis 45-46 Final Submission of Thesis 6.8.7 46 6.8.8 Relative Grading 46-47 6.8.9 Letter Grade and Weightages 47-48 6.8.10 Results of Examination and Quizzes 48

  19. (PDF) M.Tech thesis (IITP)

    PDF | On Jan 1, 2014, Nitin Kumar Singh published M.Tech thesis (IITP) | Find, read and cite all the research you need on ResearchGate

  20. (PDF) M Tech Thesis

    M Tech Thesis. July 2015; Authors: Bikram Ballav. Institute of Technical Education and Research; Download file PDF Read file. Download file PDF. Read file. Download citation. Copy link Link copied.

  21. PDF M. Tech. Thesis

    1.3 Thesis Objective and Scope. This work aims at studying the performance CFDAMA and BTDAMA MAC schemes and introducing User Prioritized-BTDAMA (BTDAMA-UP) which provide user level priority. The main focus of this work is to present the implementation of CFDAMA and BTDAMA and comparison of these protocols.

  22. MTech Theses

    Microservice-based in-network AES solution for FPGA NICs. Hussain, Lasani (IIIT-Delhi, 2022-12) Data centers demand high throughput (100 to 400 Gbps) and sub-millisecond latency. The performance of data center applications heavily depends on the efficiency of the underlying TCP stack.

  23. M Tech Thesis Format

    m Tech Thesis Format Doc - Free download as PDF File (.pdf), Text File (.txt) or read online for free. This document discusses the challenges of crafting an M Tech thesis, specifically with regards to formatting. It notes that adhering to a specific formatting style, such as the M Tech Thesis Format Doc, is a critical aspect that can impact evaluation if not followed correctly.

  24. FULL PAPER

    English document from Mapúa Institute of Technology, 128 pages, Strength Analysis of Glass Fiber-Reinforced Compressed Earth Block (GFRCEB) by Bien Marlo S. De Torres Eidref Joseph M. Paz Paulo S. Remulla A Thesis submitted to the School of Civil, Environmental and Geological Engineering in Partial Fulfillment of the

  25. Bridging the Gap Between Lab Technology and Large-Scale Application: A

    This thesis aims to provide different aspects to make the Direct Air Capture Dual Function Materials (DAC-DFM) project more applicable in commercialization and large-scale deployment to directly address the global warming problem caused by anthropogenic CO₂. Dual function materials are comprised of nano dispersed alkaline sorbents and a methanation catalyst to capture CO₂ from ambient air ...